Thermodynamics of acetone-chloroform mixtures

Alexander Apelblat; Abraham Tamir; Moshe Wagner

doi:10.1016/0378-3812(80)80018-5

Thermodynamics of acetone-chloroform mixtures

Alexander Apelblat, Abraham Tamir, Moshe Wagner

Department of Chemical Engineering

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59 Scopus citations

Abstract

Apelblat, A., Tamir, A. and Wagner, M., 1980. Thermodynamics of acetone-chloroform mixtures. Fluid Phase Equilibria, 4: 229-255. The excess thermodynamic functions G^E, H^E, S^E, C_p^E and V^E and the vapour-liquid equilibria at constant temperature, at constant pressure and azeotropic behaviour are satisfactorily described for the acetone + chloroform system using the ideal association model of the type A + B + AB + AB₂. Existing data in the literature for the system were supplemented by determination of vapour pressures at 25.0° and 35.17°C, excess volumes of mixing at 35°C and excess heat capacities at 30°C.

Original language	English
Pages (from-to)	229-255
Number of pages	27
Journal	Fluid Phase Equilibria
Volume	4
Issue number	3-4
DOIs	https://doi.org/10.1016/0378-3812(80)80018-5
State	Published - 1 Jan 1980

ASJC Scopus subject areas

General Chemical Engineering
General Physics and Astronomy
Physical and Theoretical Chemistry

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abstract = "Apelblat, A., Tamir, A. and Wagner, M., 1980. Thermodynamics of acetone-chloroform mixtures. Fluid Phase Equilibria, 4: 229-255. The excess thermodynamic functions GE, HE, SE, CpE and VE and the vapour-liquid equilibria at constant temperature, at constant pressure and azeotropic behaviour are satisfactorily described for the acetone + chloroform system using the ideal association model of the type A + B + AB + AB2. Existing data in the literature for the system were supplemented by determination of vapour pressures at 25.0° and 35.17°C, excess volumes of mixing at 35°C and excess heat capacities at 30°C.",

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AB - Apelblat, A., Tamir, A. and Wagner, M., 1980. Thermodynamics of acetone-chloroform mixtures. Fluid Phase Equilibria, 4: 229-255. The excess thermodynamic functions GE, HE, SE, CpE and VE and the vapour-liquid equilibria at constant temperature, at constant pressure and azeotropic behaviour are satisfactorily described for the acetone + chloroform system using the ideal association model of the type A + B + AB + AB2. Existing data in the literature for the system were supplemented by determination of vapour pressures at 25.0° and 35.17°C, excess volumes of mixing at 35°C and excess heat capacities at 30°C.

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Thermodynamics of acetone-chloroform mixtures

Abstract

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