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Thiophilic addition of alkyllithium to dithiocarboxylic acid anions:synthesis of 2-[bis(alkylthio)methylene]-1,3-dithioles

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9 Scopus citations

Abstract

2-lithio-4,5-disubstituted-1,3-dithioles react with CS2 in thepresence of an excess organolithium reagents yielding a product of thiophilic addition; subsequent alkylation furnished a new series of2-[bis(alkylthio)methylene]-1,3-dithioles.

Original languageEnglish
Pages (from-to)3805-3808
Number of pages4
JournalTetrahedron Letters
Volume28
Issue number33
DOIs
StatePublished - 1 Jan 1987
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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