Total synthesis of proposed auranthine

Umesh A. Kshirsagar; Vedavati G. Puranik; Narshinha P. Argade

doi:10.1021/jo100400z

Total synthesis of proposed auranthine

Umesh A. Kshirsagar, Vedavati G. Puranik, Narshinha P. Argade

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

Starting from CBz-protected glutamic anhydride and Boc-protected o-aminobenzyl amine, the first total synthesis of proposed structure of auranthine has been reported. An intramolecular aza-Wittig reaction involving a lactam carbonyl group that delivered the diazepine core unit was the key step in the synthesis.

Original language	English
Pages (from-to)	2702-2705
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	75
Issue number	8
DOIs	https://doi.org/10.1021/jo100400z
State	Published - 16 Apr 2010
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

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title = "Total synthesis of proposed auranthine",

abstract = "Starting from CBz-protected glutamic anhydride and Boc-protected o-aminobenzyl amine, the first total synthesis of proposed structure of auranthine has been reported. An intramolecular aza-Wittig reaction involving a lactam carbonyl group that delivered the diazepine core unit was the key step in the synthesis.",

author = "Kshirsagar, {Umesh A.} and Puranik, {Vedavati G.} and Argade, {Narshinha P.}",

year = "2010",

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T1 - Total synthesis of proposed auranthine

AU - Kshirsagar, Umesh A.

AU - Puranik, Vedavati G.

AU - Argade, Narshinha P.

PY - 2010/4/16

Y1 - 2010/4/16

N2 - Starting from CBz-protected glutamic anhydride and Boc-protected o-aminobenzyl amine, the first total synthesis of proposed structure of auranthine has been reported. An intramolecular aza-Wittig reaction involving a lactam carbonyl group that delivered the diazepine core unit was the key step in the synthesis.

AB - Starting from CBz-protected glutamic anhydride and Boc-protected o-aminobenzyl amine, the first total synthesis of proposed structure of auranthine has been reported. An intramolecular aza-Wittig reaction involving a lactam carbonyl group that delivered the diazepine core unit was the key step in the synthesis.

UR - http://www.scopus.com/inward/record.url?scp=77951007611&partnerID=8YFLogxK

U2 - 10.1021/jo100400z

DO - 10.1021/jo100400z

M3 - Article

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VL - 75

SP - 2702

EP - 2705

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 8

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Total synthesis of proposed auranthine

Abstract

ASJC Scopus subject areas

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