The heating of the ionic complex [CpMn(CO)2(NO)] +SnCl3- (I) in methylene chloride gives a neutral complex CpMn(CO)(NO) SnCl3 (II). The latter reacts with lithium phenylacetylenide to yield a complex CpMn(CO)(NO) Sn(C≡CPh)3 (III). According to the X-ray diffraction data, complexes II and III contain shortened Mn-Sn bonds (2.5178(5) and 2.5436(12) Å, respectively).
|Number of pages||5|
|Journal||Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya|
|State||Published - 1 Apr 2010|
ASJC Scopus subject areas
- Chemistry (all)
- Chemical Engineering (all)