Trichlorostannyl and tris(phenylacetylenide) stannyl complexes of manganese cyclopentadienylcarbonylnitrosyl: Synthesis and molecular structures

A. I. Blokhin; A. A. Pasynskii; Yu V. Torubaev; M. Scheer

doi:10.1134/S107032841004007X

Trichlorostannyl and tris(phenylacetylenide) stannyl complexes of manganese cyclopentadienylcarbonylnitrosyl: Synthesis and molecular structures

A. I. Blokhin, A. A. Pasynskii, Yu V. Torubaev, M. Scheer

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9 Scopus citations

Abstract

The heating of the ionic complex [CpMn(CO)₂(NO)] ⁺SnCl₃- (I) in methylene chloride gives a neutral complex CpMn(CO)(NO) SnCl₃ (II). The latter reacts with lithium phenylacetylenide to yield a complex CpMn(CO)(NO) Sn(C≡CPh)₃ (III). According to the X-ray diffraction data, complexes II and III contain shortened Mn-Sn bonds (2.5178(5) and 2.5436(12) Å, respectively).

Original language	English
Pages (from-to)	284-288
Number of pages	5
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	36
Issue number	4
DOIs	https://doi.org/10.1134/S107032841004007X
State	Published - 1 Apr 2010
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

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10.1134/S107032841004007X

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title = "Trichlorostannyl and tris(phenylacetylenide) stannyl complexes of manganese cyclopentadienylcarbonylnitrosyl: Synthesis and molecular structures",

abstract = "The heating of the ionic complex [CpMn(CO)2(NO)] +SnCl3- (I) in methylene chloride gives a neutral complex CpMn(CO)(NO) SnCl3 (II). The latter reacts with lithium phenylacetylenide to yield a complex CpMn(CO)(NO) Sn(C≡CPh)3 (III). According to the X-ray diffraction data, complexes II and III contain shortened Mn-Sn bonds (2.5178(5) and 2.5436(12) {\AA}, respectively).",

author = "Blokhin, {A. I.} and Pasynskii, {A. A.} and Torubaev, {Yu V.} and M. Scheer",

note = "Funding Information: This work was supported by the Russian Founda tion for Bacic Research (project no. 09 03 00961) and grant nos. OX1.3 and 8P22.",

year = "2010",

month = apr,

day = "1",

doi = "10.1134/S107032841004007X",

language = "English",

volume = "36",

pages = "284--288",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

issn = "1070-3284",

publisher = "Pleiades Publishing",

number = "4",

}

Trichlorostannyl and tris(phenylacetylenide) stannyl complexes of manganese cyclopentadienylcarbonylnitrosyl: Synthesis and molecular structures. / Blokhin, A. I.; Pasynskii, A. A.; Torubaev, Yu V. et al.
In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 36, No. 4, 01.04.2010, p. 284-288.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Trichlorostannyl and tris(phenylacetylenide) stannyl complexes of manganese cyclopentadienylcarbonylnitrosyl

T2 - Synthesis and molecular structures

AU - Blokhin, A. I.

AU - Pasynskii, A. A.

AU - Torubaev, Yu V.

AU - Scheer, M.

N1 - Funding Information: This work was supported by the Russian Founda tion for Bacic Research (project no. 09 03 00961) and grant nos. OX1.3 and 8P22.

PY - 2010/4/1

Y1 - 2010/4/1

N2 - The heating of the ionic complex [CpMn(CO)2(NO)] +SnCl3- (I) in methylene chloride gives a neutral complex CpMn(CO)(NO) SnCl3 (II). The latter reacts with lithium phenylacetylenide to yield a complex CpMn(CO)(NO) Sn(C≡CPh)3 (III). According to the X-ray diffraction data, complexes II and III contain shortened Mn-Sn bonds (2.5178(5) and 2.5436(12) Å, respectively).

AB - The heating of the ionic complex [CpMn(CO)2(NO)] +SnCl3- (I) in methylene chloride gives a neutral complex CpMn(CO)(NO) SnCl3 (II). The latter reacts with lithium phenylacetylenide to yield a complex CpMn(CO)(NO) Sn(C≡CPh)3 (III). According to the X-ray diffraction data, complexes II and III contain shortened Mn-Sn bonds (2.5178(5) and 2.5436(12) Å, respectively).

UR - http://www.scopus.com/inward/record.url?scp=77953328995&partnerID=8YFLogxK

U2 - 10.1134/S107032841004007X

DO - 10.1134/S107032841004007X

M3 - Article

AN - SCOPUS:77953328995

SN - 1070-3284

VL - 36

SP - 284

EP - 288

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

IS - 4

ER -

Trichlorostannyl and tris(phenylacetylenide) stannyl complexes of manganese cyclopentadienylcarbonylnitrosyl: Synthesis and molecular structures

Abstract

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