Ultrafast generation of aqueous carbonic acid

Katrin Adamczyk; Mirabelle Prémont-Schwarz; Dina Pines; Ehud Pines; Erik T.J. Nibbering

doi:10.1364/up.2010.tud5

Ultrafast generation of aqueous carbonic acid

Katrin Adamczyk, Mirabelle Prémont-Schwarz, Dina Pines, Ehud Pines, Erik T.J. Nibbering

Department of Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

We generate carbonic acid, a molecule of elusive nature, by ultrafast protonation of bicarbonate in aqueous solution, which follows the free energy reactivity correlation known for carboxylate anions, with an associated pK_a-value of 3.45 ± 0.15.

Original language	English
Title of host publication	International Conference on Ultrafast Phenomena, UP 2010
Publisher	Optical Society of America (OSA)
ISBN (Print)	9781557528940
DOIs	https://doi.org/10.1364/up.2010.tud5
State	Published - 1 Jan 2010
Event	International Conference on Ultrafast Phenomena, UP 2010 - Snowmass Village, CO, United States Duration: 18 Jul 2010 → 23 Jul 2010

Publication series

Name	Optics InfoBase Conference Papers
ISSN (Electronic)	2162-2701

Conference

Conference	International Conference on Ultrafast Phenomena, UP 2010
Country/Territory	United States
City	Snowmass Village, CO
Period	18/07/10 → 23/07/10

ASJC Scopus subject areas

Instrumentation
Atomic and Molecular Physics, and Optics

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10.1364/up.2010.tud5

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title = "Ultrafast generation of aqueous carbonic acid",

abstract = "We generate carbonic acid, a molecule of elusive nature, by ultrafast protonation of bicarbonate in aqueous solution, which follows the free energy reactivity correlation known for carboxylate anions, with an associated pKa-value of 3.45 ± 0.15.",

author = "Katrin Adamczyk and Mirabelle Pr{\'e}mont-Schwarz and Dina Pines and Ehud Pines and Nibbering, {Erik T.J.}",

year = "2010",

month = jan,

day = "1",

doi = "10.1364/up.2010.tud5",

language = "English",

isbn = "9781557528940",

series = "Optics InfoBase Conference Papers",

publisher = "Optical Society of America (OSA)",

booktitle = "International Conference on Ultrafast Phenomena, UP 2010",

note = "International Conference on Ultrafast Phenomena, UP 2010 ; Conference date: 18-07-2010 Through 23-07-2010",

}

Adamczyk, K, Prémont-Schwarz, M, Pines, D, Pines, E & Nibbering, ETJ 2010, Ultrafast generation of aqueous carbonic acid. in International Conference on Ultrafast Phenomena, UP 2010. Optics InfoBase Conference Papers, Optical Society of America (OSA), International Conference on Ultrafast Phenomena, UP 2010, Snowmass Village, CO, United States, 18/07/10. https://doi.org/10.1364/up.2010.tud5

TY - GEN

T1 - Ultrafast generation of aqueous carbonic acid

AU - Adamczyk, Katrin

AU - Prémont-Schwarz, Mirabelle

AU - Pines, Dina

AU - Pines, Ehud

AU - Nibbering, Erik T.J.

PY - 2010/1/1

Y1 - 2010/1/1

N2 - We generate carbonic acid, a molecule of elusive nature, by ultrafast protonation of bicarbonate in aqueous solution, which follows the free energy reactivity correlation known for carboxylate anions, with an associated pKa-value of 3.45 ± 0.15.

AB - We generate carbonic acid, a molecule of elusive nature, by ultrafast protonation of bicarbonate in aqueous solution, which follows the free energy reactivity correlation known for carboxylate anions, with an associated pKa-value of 3.45 ± 0.15.

UR - http://www.scopus.com/inward/record.url?scp=85088754733&partnerID=8YFLogxK

U2 - 10.1364/up.2010.tud5

DO - 10.1364/up.2010.tud5

M3 - Conference contribution

AN - SCOPUS:85088754733

SN - 9781557528940

T3 - Optics InfoBase Conference Papers

BT - International Conference on Ultrafast Phenomena, UP 2010

PB - Optical Society of America (OSA)

T2 - International Conference on Ultrafast Phenomena, UP 2010

Y2 - 18 July 2010 through 23 July 2010

ER -

Ultrafast generation of aqueous carbonic acid

Abstract

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Conference

ASJC Scopus subject areas

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