TY - JOUR
T1 - Universal Origin for Environment-Assisted Quantum Transport in Exciton Transfer Networks
AU - Zerah-Harush, Elinor
AU - Dubi, Yonatan
N1 - Publisher Copyright:
© 2018 American Chemical Society.
PY - 2018/4/5
Y1 - 2018/4/5
N2 - Environment-assisted quantum transport (ENAQT) is the possibility of an external environment to enhance transport efficiency of quantum particles. This idea has generated much excitement over recent years, especially due to the experimentally motivated possibility of ENAQT in photosynthetic exciton transfer complexes. Many theoretical calculations have shown ENAQT, but the explanations for its origin differ, and a universal explanation has been elusive. Here we demonstrate a universal origin for ENAQT in quantum networks with a dephasing environment, based on a relation between exciton current and occupation within a Markovian open quantum system approach. We show that ENAQT appears due to two competing processes, namely, the tendency of dephasing to make the exciton population uniform, and the formation of an exciton density gradient, defined by the source and the sink. Furthermore, we find a geometric condition on the network for the appearance of ENAQT, relevant to natural and artificial systems.
AB - Environment-assisted quantum transport (ENAQT) is the possibility of an external environment to enhance transport efficiency of quantum particles. This idea has generated much excitement over recent years, especially due to the experimentally motivated possibility of ENAQT in photosynthetic exciton transfer complexes. Many theoretical calculations have shown ENAQT, but the explanations for its origin differ, and a universal explanation has been elusive. Here we demonstrate a universal origin for ENAQT in quantum networks with a dephasing environment, based on a relation between exciton current and occupation within a Markovian open quantum system approach. We show that ENAQT appears due to two competing processes, namely, the tendency of dephasing to make the exciton population uniform, and the formation of an exciton density gradient, defined by the source and the sink. Furthermore, we find a geometric condition on the network for the appearance of ENAQT, relevant to natural and artificial systems.
UR - http://www.scopus.com/inward/record.url?scp=85045016832&partnerID=8YFLogxK
U2 - 10.1021/acs.jpclett.7b03306
DO - 10.1021/acs.jpclett.7b03306
M3 - Article
C2 - 29537848
AN - SCOPUS:85045016832
SN - 1948-7185
VL - 9
SP - 1689
EP - 1695
JO - Journal of Physical Chemistry Letters
JF - Journal of Physical Chemistry Letters
IS - 7
ER -