Unusual dimerization of N-protected bromomethylindoles/benzyl bromide with arylmetal halides: generation of indolylmethyl/benzyl radical

Neelamegam Ramesh; Chandran Prakash; Radhakrishnan Sureshbabu; Vasudevan Dhayalan; Arasambattu K. Mohanakrishnan

doi:10.1016/j.tet.2007.12.047

Unusual dimerization of N-protected bromomethylindoles/benzyl bromide with arylmetal halides: generation of indolylmethyl/benzyl radical

Neelamegam Ramesh, Chandran Prakash, Radhakrishnan Sureshbabu, Vasudevan Dhayalan, Arasambattu K. Mohanakrishnan

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

A detailed study on the interaction of N-protected bromomethylindoles with various types of aryl/alkyl Grignard is reported. Full experimental details on the mechanism of the unusual dimerization reaction are presented.

Original language	English
Pages (from-to)	2071-2079
Number of pages	9
Journal	Tetrahedron
Volume	64
Issue number	9
DOIs	https://doi.org/10.1016/j.tet.2007.12.047
State	Published - 25 Feb 2008
Externally published	Yes

Keywords

Alkyl/aryl Grignard
Benzylbromide
Bromomethylindole
Indolylmethyl/benzyl radical

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tet.2007.12.047

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title = "Unusual dimerization of N-protected bromomethylindoles/benzyl bromide with arylmetal halides: generation of indolylmethyl/benzyl radical",

abstract = "A detailed study on the interaction of N-protected bromomethylindoles with various types of aryl/alkyl Grignard is reported. Full experimental details on the mechanism of the unusual dimerization reaction are presented.",

keywords = "Alkyl/aryl Grignard, Benzylbromide, Bromomethylindole, Indolylmethyl/benzyl radical",

author = "Neelamegam Ramesh and Chandran Prakash and Radhakrishnan Sureshbabu and Vasudevan Dhayalan and Mohanakrishnan, {Arasambattu K.}",

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language = "English",

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T1 - Unusual dimerization of N-protected bromomethylindoles/benzyl bromide with arylmetal halides

T2 - generation of indolylmethyl/benzyl radical

AU - Ramesh, Neelamegam

AU - Prakash, Chandran

AU - Sureshbabu, Radhakrishnan

AU - Dhayalan, Vasudevan

AU - Mohanakrishnan, Arasambattu K.

PY - 2008/2/25

Y1 - 2008/2/25

N2 - A detailed study on the interaction of N-protected bromomethylindoles with various types of aryl/alkyl Grignard is reported. Full experimental details on the mechanism of the unusual dimerization reaction are presented.

AB - A detailed study on the interaction of N-protected bromomethylindoles with various types of aryl/alkyl Grignard is reported. Full experimental details on the mechanism of the unusual dimerization reaction are presented.

KW - Alkyl/aryl Grignard

KW - Benzylbromide

KW - Bromomethylindole

KW - Indolylmethyl/benzyl radical

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U2 - 10.1016/j.tet.2007.12.047

DO - 10.1016/j.tet.2007.12.047

M3 - Article

AN - SCOPUS:38549176722

SN - 0040-4020

VL - 64

SP - 2071

EP - 2079

JO - Tetrahedron

JF - Tetrahedron

IS - 9

ER -

Unusual dimerization of N-protected bromomethylindoles/benzyl bromide with arylmetal halides: generation of indolylmethyl/benzyl radical

Abstract

Keywords

ASJC Scopus subject areas

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