Unusual iron-platinum bonding in the cluster (diironhexacarbonyl)-[(π-dicyclopentadiene)platinum] disulfide

A. A. Pasynskii; N. I. Semenova; Yu V. Torubaev; K. A. Lysenko

Unusual iron-platinum bonding in the cluster (diironhexacarbonyl)-[(π-dicyclopentadiene)platinum] disulfide

A. A. Pasynskii, N. I. Semenova, Yu V. Torubaev, K. A. Lysenko

Research output: Contribution to journal › Article › peer-review

Abstract

The new C₁₀H₁₂Pt(μ₃-S)₂Fe ₂(CO)₆ cluster was prepared by transmetallalion of (μ₃-S)₂Fe₃(CO)₉ with C₁₀H₁₂PtCl₂, and its structure was established by X-ray diffraction analysis. The platinum atom has a planar-square coordination formed by the π-coordinated double bonds of the dicyclopentadiene ligand and two μ₃-bridging sulfur atoms. Two Fe(CO)₃ fragments are linked through the Fe-Fe bond (2.515 Å). In addition, one iron atom is involved in the Fe-Pt bonding (3.03 Å). As a result, the plane of the ligand environment of the platinum atom is inclined toward this iron atom. The role of steric effects, of ligand-ligand repulsions in the manifestation of the iron-platinum interaction is discussed.

Original language	English
Pages (from-to)	1807-1809
Number of pages	3
Journal	Russian Journal of Inorganic Chemistry
Volume	46
Issue number	12
State	Published - 1 Jan 2001
Externally published	Yes

ASJC Scopus subject areas

Materials Science (miscellaneous)
Physical and Theoretical Chemistry
Inorganic Chemistry

Cite this

@article{c06a55e6a3e34fb7bd80daa2a7bbc0ba,

title = "Unusual iron-platinum bonding in the cluster (diironhexacarbonyl)-[(π-dicyclopentadiene)platinum] disulfide",

abstract = "The new C10H12Pt(μ3-S)2Fe 2(CO)6 cluster was prepared by transmetallalion of (μ3-S)2Fe3(CO)9 with C10H12PtCl2, and its structure was established by X-ray diffraction analysis. The platinum atom has a planar-square coordination formed by the π-coordinated double bonds of the dicyclopentadiene ligand and two μ3-bridging sulfur atoms. Two Fe(CO)3 fragments are linked through the Fe-Fe bond (2.515 {\AA}). In addition, one iron atom is involved in the Fe-Pt bonding (3.03 {\AA}). As a result, the plane of the ligand environment of the platinum atom is inclined toward this iron atom. The role of steric effects, of ligand-ligand repulsions in the manifestation of the iron-platinum interaction is discussed.",

author = "Pasynskii, {A. A.} and Semenova, {N. I.} and Torubaev, {Yu V.} and Lysenko, {K. A.}",

year = "2001",

month = jan,

day = "1",

language = "English",

volume = "46",

pages = "1807--1809",

journal = "Russian Journal of Inorganic Chemistry",

issn = "0036-0236",

publisher = "Pleiades Publishing",

number = "12",

}

TY - JOUR

T1 - Unusual iron-platinum bonding in the cluster (diironhexacarbonyl)-[(π-dicyclopentadiene)platinum] disulfide

AU - Pasynskii, A. A.

AU - Semenova, N. I.

AU - Torubaev, Yu V.

AU - Lysenko, K. A.

PY - 2001/1/1

Y1 - 2001/1/1

N2 - The new C10H12Pt(μ3-S)2Fe 2(CO)6 cluster was prepared by transmetallalion of (μ3-S)2Fe3(CO)9 with C10H12PtCl2, and its structure was established by X-ray diffraction analysis. The platinum atom has a planar-square coordination formed by the π-coordinated double bonds of the dicyclopentadiene ligand and two μ3-bridging sulfur atoms. Two Fe(CO)3 fragments are linked through the Fe-Fe bond (2.515 Å). In addition, one iron atom is involved in the Fe-Pt bonding (3.03 Å). As a result, the plane of the ligand environment of the platinum atom is inclined toward this iron atom. The role of steric effects, of ligand-ligand repulsions in the manifestation of the iron-platinum interaction is discussed.

AB - The new C10H12Pt(μ3-S)2Fe 2(CO)6 cluster was prepared by transmetallalion of (μ3-S)2Fe3(CO)9 with C10H12PtCl2, and its structure was established by X-ray diffraction analysis. The platinum atom has a planar-square coordination formed by the π-coordinated double bonds of the dicyclopentadiene ligand and two μ3-bridging sulfur atoms. Two Fe(CO)3 fragments are linked through the Fe-Fe bond (2.515 Å). In addition, one iron atom is involved in the Fe-Pt bonding (3.03 Å). As a result, the plane of the ligand environment of the platinum atom is inclined toward this iron atom. The role of steric effects, of ligand-ligand repulsions in the manifestation of the iron-platinum interaction is discussed.

UR - http://www.scopus.com/inward/record.url?scp=3342950235&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:3342950235

SN - 0036-0236

VL - 46

SP - 1807

EP - 1809

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

IS - 12

ER -

Unusual iron-platinum bonding in the cluster (diironhexacarbonyl)-[(π-dicyclopentadiene)platinum] disulfide

Abstract

ASJC Scopus subject areas

Other files and links

Fingerprint

Cite this