Unusual rearrangement of modified PNP ligand based Ru complexes relevant to alcohol dehydrogenation catalysis

Shubham Deolka; Naziha Tarannam; Robert R. Fayzullin; Sebastian Kozuch; Eugene Khaskin

doi:10.1039/c9cc06024c

Unusual rearrangement of modified PNP ligand based Ru complexes relevant to alcohol dehydrogenation catalysis

Shubham Deolka
, Naziha Tarannam
, Robert R. Fayzullin
, Sebastian Kozuch
, Eugene Khaskin

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

'Hangman-type' PNP pincer ligands and their associated Ru complexes undergo sp²-sp³ C-C bond cleavage and subsequent C-C formation processes to form a new, one carbon unit longer backbone motif. DFT and mechanistic studies suggest a mechanism dependent upon arm pyridine coordination and ligand sterics.

Original language	English
Pages (from-to)	11350-11353
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	76
DOIs	https://doi.org/10.1039/c9cc06024c
State	Published - 1 Jan 2019

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Unusual rearrangement of modified PNP ligand based Ru complexes relevant to alcohol dehydrogenation catalysis",

abstract = "'Hangman-type' PNP pincer ligands and their associated Ru complexes undergo sp2-sp3 C-C bond cleavage and subsequent C-C formation processes to form a new, one carbon unit longer backbone motif. DFT and mechanistic studies suggest a mechanism dependent upon arm pyridine coordination and ligand sterics.",

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T1 - Unusual rearrangement of modified PNP ligand based Ru complexes relevant to alcohol dehydrogenation catalysis

AU - Deolka, Shubham

AU - Tarannam, Naziha

AU - Fayzullin, Robert R.

AU - Kozuch, Sebastian

AU - Khaskin, Eugene

PY - 2019/1/1

Y1 - 2019/1/1

N2 - 'Hangman-type' PNP pincer ligands and their associated Ru complexes undergo sp2-sp3 C-C bond cleavage and subsequent C-C formation processes to form a new, one carbon unit longer backbone motif. DFT and mechanistic studies suggest a mechanism dependent upon arm pyridine coordination and ligand sterics.

AB - 'Hangman-type' PNP pincer ligands and their associated Ru complexes undergo sp2-sp3 C-C bond cleavage and subsequent C-C formation processes to form a new, one carbon unit longer backbone motif. DFT and mechanistic studies suggest a mechanism dependent upon arm pyridine coordination and ligand sterics.

UR - https://www.scopus.com/pages/publications/85072509177

U2 - 10.1039/c9cc06024c

DO - 10.1039/c9cc06024c

M3 - Article

AN - SCOPUS:85072509177

SN - 1359-7345

VL - 55

SP - 11350

EP - 11353

JO - Chemical Communications

JF - Chemical Communications

IS - 76

ER -

Unusual rearrangement of modified PNP ligand based Ru complexes relevant to alcohol dehydrogenation catalysis

Abstract

ASJC Scopus subject areas

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