Unusual spin-spin interactions across the coordination bond in hexacoordinate silicon complexes: Crystal-structure coupling relationship

Inna Kalikhman, Sonia Krivonos, Dietmar Stalke, Thomas Kottke, Daniel Kost

Research output: Contribution to journalArticlepeer-review

34 Scopus citations

Abstract

Two-, three-, and even four-bond coupling constants are reported for the first time across the N→Si coordination bond in neutral, hexacoordinate silicon chelates. Two-bond coupling constants depend critically on bond angles, and three-bond couplings follow a Karplus-type correlation with dihedral angles obtained from X-ray crystallographic analyses.

Original languageEnglish
Pages (from-to)3255-3257
Number of pages3
JournalOrganometallics
Volume16
Issue number15
DOIs
StatePublished - 22 Jul 1997

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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