Unusual spontaneous oxidation of 2,2′-(quinolin-2-ylmethylene)bis(1H-indene-1,3(2H)-dione): An experimental and theoretical study of the mechanism

Keyphrases

• Aldehydes 100%
• Indane-1,3-dione 100%
• Quinoline 100%
• Spontaneous Oxidation 100%
• Dioxo 66%
• Self-oxidation 66%
• Elemental Analysis 33%
• Transition State 33%
• Oxidation Products 33%
• Methyl 33%
• Proton Transfer 33%
• NMR Analysis 33%
• Bromo 33%
• Bromination 33%
• Methylene 33%
• Reaction Coordinate 33%
• Free Energy Barrier 33%
• Ylidenes 33%
• Nitrogen Atom 33%
• 1,3-Indandione 33%
• Cycloalkanones 33%
• 2-Pyridinecarboxaldehyde 33%
• Unusual Reactions 33%
• Michael Adducts 33%
• Pre-reaction Complex 33%
• Pyridinic Nitrogen 33%
• Tribromide 33%
• Quinolinium 33%
• Hydride Ion Transfer 33%

Chemistry

• 1H-Indene 100%
• Transition State 50%
• NMR Spectroscopy 50%
• Gibbs Free Energy 50%
• Michael Reaction 50%
• Proton Transfer 50%
• Energy Barrier 50%
• Nitrogen Atom 50%
• Complex Reaction Mechanisms 50%
• 1,3-indandione 50%
• Elemental Analysis 50%
• Pyridinecarbaldehyde 50%