Vibrational analysis of the X2(3/2)-X1(1/2) infrared system of BiO

C. Linton, R. Bacis, F. Martin, S. Rosenwaks, J. Vergès

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Abstract

The vibrational analysis of the X2 (3/2)-X1 (1/2) system of BiO in the near infrared region, 6400-7700 cm-1, has been extended. Transitions in the Δv = - 1, 0, and + 1 sequences have been observed and assigned up to v = 6 in the upper state and no transitions have been observed with v′ > 6. The Δv = - 1 sequence is shown to form a head of heads. The upper state appears to be strongly perturbed, especially at v = 6.

Original languageEnglish
Pages (from-to)3422-3425
Number of pages4
JournalJournal of Chemical Physics
Volume96
Issue number5
DOIs
StatePublished - 1 Jan 1992

ASJC Scopus subject areas

  • Physics and Astronomy (all)
  • Physical and Theoretical Chemistry

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