Vibrational analysis of the X2(3/2)-X1(1/2) infrared system of BiO

C. Linton; R. Bacis; F. Martin; S. Rosenwaks; J. Vergès

doi:10.1063/1.461944

Vibrational analysis of the X₂(3/2)-X₁(1/2) infrared system of BiO

C. Linton, R. Bacis, F. Martin, S. Rosenwaks, J. Vergès

Department of Physics

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6 Scopus citations

Abstract

The vibrational analysis of the X₂ (3/2)-X₁ (1/2) system of BiO in the near infrared region, 6400-7700 cm^-1, has been extended. Transitions in the Δv = - 1, 0, and + 1 sequences have been observed and assigned up to v = 6 in the upper state and no transitions have been observed with v′ > 6. The Δv = - 1 sequence is shown to form a head of heads. The upper state appears to be strongly perturbed, especially at v = 6.

Original language	English
Pages (from-to)	3422-3425
Number of pages	4
Journal	Journal of Chemical Physics
Volume	96
Issue number	5
DOIs	https://doi.org/10.1063/1.461944
State	Published - 1 Jan 1992

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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abstract = "The vibrational analysis of the X2 (3/2)-X1 (1/2) system of BiO in the near infrared region, 6400-7700 cm-1, has been extended. Transitions in the Δv = - 1, 0, and + 1 sequences have been observed and assigned up to v = 6 in the upper state and no transitions have been observed with v′ > 6. The Δv = - 1 sequence is shown to form a head of heads. The upper state appears to be strongly perturbed, especially at v = 6.",

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AU - Rosenwaks, S.

AU - Vergès, J.

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N2 - The vibrational analysis of the X2 (3/2)-X1 (1/2) system of BiO in the near infrared region, 6400-7700 cm-1, has been extended. Transitions in the Δv = - 1, 0, and + 1 sequences have been observed and assigned up to v = 6 in the upper state and no transitions have been observed with v′ > 6. The Δv = - 1 sequence is shown to form a head of heads. The upper state appears to be strongly perturbed, especially at v = 6.

AB - The vibrational analysis of the X2 (3/2)-X1 (1/2) system of BiO in the near infrared region, 6400-7700 cm-1, has been extended. Transitions in the Δv = - 1, 0, and + 1 sequences have been observed and assigned up to v = 6 in the upper state and no transitions have been observed with v′ > 6. The Δv = - 1 sequence is shown to form a head of heads. The upper state appears to be strongly perturbed, especially at v = 6.

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Vibrational analysis of the X₂(3/2)-X₁(1/2) infrared system of BiO

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