Vibrationally excited states of CH3CFCl2: Intramolecular vibrational redistribution and photodissociation dynamics

A. Melchior; X. Chen; I. Bar; S. Rosenwaks

doi:10.1063/1.481752

Vibrationally excited states of CH₃CFCl₂: Intramolecular vibrational redistribution and photodissociation dynamics

A. Melchior, X. Chen, I. Bar, S. Rosenwaks

Department of Physics

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

The effect of initial vibrational excitation on product branching are explored. The spectral features and the time scales for intermolecular energy transfer in the region of the second and third overtones of CH₃ in hydrochlorofluoroethane (HCFC). The photodissociation studies allow the determination of the spin-orbit branching ratios, which are measures of the involved potential energy surface (PES) and the adiabatic and nonadiabatic interplay during photodissociation.

Original language	English
Pages (from-to)	10787-10795
Number of pages	9
Journal	Journal of Chemical Physics
Volume	112
Issue number	24
DOIs	https://doi.org/10.1063/1.481752
State	Published - 22 Jun 2000

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.481752

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title = "Vibrationally excited states of CH3CFCl2: Intramolecular vibrational redistribution and photodissociation dynamics",

abstract = "The effect of initial vibrational excitation on product branching are explored. The spectral features and the time scales for intermolecular energy transfer in the region of the second and third overtones of CH3 in hydrochlorofluoroethane (HCFC). The photodissociation studies allow the determination of the spin-orbit branching ratios, which are measures of the involved potential energy surface (PES) and the adiabatic and nonadiabatic interplay during photodissociation.",

author = "A. Melchior and X. Chen and I. Bar and S. Rosenwaks",

year = "2000",

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T1 - Vibrationally excited states of CH3CFCl2

T2 - Intramolecular vibrational redistribution and photodissociation dynamics

AU - Melchior, A.

AU - Chen, X.

AU - Bar, I.

AU - Rosenwaks, S.

PY - 2000/6/22

Y1 - 2000/6/22

N2 - The effect of initial vibrational excitation on product branching are explored. The spectral features and the time scales for intermolecular energy transfer in the region of the second and third overtones of CH3 in hydrochlorofluoroethane (HCFC). The photodissociation studies allow the determination of the spin-orbit branching ratios, which are measures of the involved potential energy surface (PES) and the adiabatic and nonadiabatic interplay during photodissociation.

AB - The effect of initial vibrational excitation on product branching are explored. The spectral features and the time scales for intermolecular energy transfer in the region of the second and third overtones of CH3 in hydrochlorofluoroethane (HCFC). The photodissociation studies allow the determination of the spin-orbit branching ratios, which are measures of the involved potential energy surface (PES) and the adiabatic and nonadiabatic interplay during photodissociation.

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U2 - 10.1063/1.481752

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M3 - Article

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JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

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ER -

Vibrationally excited states of CH₃CFCl₂: Intramolecular vibrational redistribution and photodissociation dynamics

Abstract

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