Vibrationally mediated photodissociation of jet-cooled CH₃CF₂Cl: A probe of energy flow and bond breaking dynamics

Keyphrases

• Energy Flow 100%
• Overtone 100%
• Bond Breaking 100%
• Vibrationally Mediated Photodissociation 100%
• Stretching Deformation 100%
• Methyl 66%
• Photofragment 66%
• Local Resonance 66%
• Room Temperature 33%
• Branching Ratio 33%
• Laser Beams 33%
• Congestion 33%
• Time-of-flight Mass Spectrometry 33%
• Peak Structure 33%
• Deformation State 33%
• UV Laser 33%
• Action Spectrum 33%
• Frequency Peaks 33%
• Multiple Peaks 33%
• Double Resonance 33%
• Photodissociation 33%
• Pre-excitation 33%
• Multiphoton Ionization 33%
• Photoacoustic Spectrum 33%
• IR Excitation 33%
• Dark State 33%
• Vibrationless 33%
• Fermi Resonance 33%
• Vibrational Energy Redistribution 33%
• Resonance Scheme 33%
• Photodissociation Dynamics 33%

Chemistry

• Jet 100%
• Photodissociation 100%
• Ground State 33%
• Ambient Reaction Temperature 33%
• Double Resonance 33%
• Matrix-Assisted Laser Desorption-Ionization 33%
• Multiphoton Ionization (MPI) 33%
• Fermi Resonance 33%
• Photoacoustic Spectra 33%
• Vibrational Energy Redistribution 33%