Vibronic Localization of the Electronic Pair in Polynuclear Mixed-Valence Polyoxometalates

J. J. Borrás-Almenar, J. M. Clemente, E. Coronado, B. S. Tsukerblat, A. V. Palii

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

A general approach to the vibronic problem of delocalized electronic pairs in mixed-valence compounds is developed and applied to understand the ways of electron delocalization in dodecanuclear polyoxometalate clusters containing two moving electrons. The interplay between electronic and vibronic interactions is examined. The influence of vibronic interaction on the nature of the spin of the ground state is considered.

Original languageEnglish
Pages (from-to)463-470
Number of pages8
JournalZeitschrift fur Physikalische Chemie
Volume201
Issue number1-2
DOIs
StatePublished - 30 May 1997
Externally publishedYes

Keywords

  • Magnetic properties
  • Mixed-valency
  • Polyoxometalates
  • Vibronic interaction

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

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