Volumetric properties of 1,2-dimethylbenzene + ethyl acrylate, butyl acrylate, methyl methacrylate, and styrene at 298.15 K

René D. Peralta; Ramiro Infante; Gladis Cortez; J. Román Torres-Lubián; Jaime Wisniak

doi:10.1016/s0040-6031(02)00605-6

Volumetric properties of 1,2-dimethylbenzene + ethyl acrylate, butyl acrylate, methyl methacrylate, and styrene at 298.15 K

René D. Peralta, Ramiro Infante, Gladis Cortez, J. Román Torres-Lubián, Jaime Wisniak

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Densities of the binary systems of 1,2-dimethylbenzene with ethyl acrylate (EA), butyl acrylate (BA), methyl methacrylate (MMA), and styrene have been measured as a function of the composition, at 298.15 K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess volumes (V^E) were correlated with the Redlich-Kister equation. The excess volumes are positive for the binaries of o-xylene with MMA and styrene, and negative for o-xylene + butyl acrylate. All systems present small deviations from ideality; the system o-xylene + ethyl acrylate is closest to ideality.

Original language	English
Pages (from-to)	247-252
Number of pages	6
Journal	Thermochimica Acta
Volume	402
Issue number	1-2
DOIs	https://doi.org/10.1016/s0040-6031(02)00605-6
State	Published - 3 Jun 2003

Keywords

1,2-Dimethylbenzene
Acrylates
Densities
Excess volumes
Monomers
Styrene

ASJC Scopus subject areas

Instrumentation
Condensed Matter Physics
Physical and Theoretical Chemistry

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10.1016/s0040-6031(02)00605-6

Cite this

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title = "Volumetric properties of 1,2-dimethylbenzene + ethyl acrylate, butyl acrylate, methyl methacrylate, and styrene at 298.15 K",

abstract = "Densities of the binary systems of 1,2-dimethylbenzene with ethyl acrylate (EA), butyl acrylate (BA), methyl methacrylate (MMA), and styrene have been measured as a function of the composition, at 298.15 K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess volumes (VE) were correlated with the Redlich-Kister equation. The excess volumes are positive for the binaries of o-xylene with MMA and styrene, and negative for o-xylene + butyl acrylate. All systems present small deviations from ideality; the system o-xylene + ethyl acrylate is closest to ideality.",

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T1 - Volumetric properties of 1,2-dimethylbenzene + ethyl acrylate, butyl acrylate, methyl methacrylate, and styrene at 298.15 K

AU - Peralta, René D.

AU - Infante, Ramiro

AU - Cortez, Gladis

AU - Torres-Lubián, J. Román

AU - Wisniak, Jaime

PY - 2003/6/3

Y1 - 2003/6/3

N2 - Densities of the binary systems of 1,2-dimethylbenzene with ethyl acrylate (EA), butyl acrylate (BA), methyl methacrylate (MMA), and styrene have been measured as a function of the composition, at 298.15 K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess volumes (VE) were correlated with the Redlich-Kister equation. The excess volumes are positive for the binaries of o-xylene with MMA and styrene, and negative for o-xylene + butyl acrylate. All systems present small deviations from ideality; the system o-xylene + ethyl acrylate is closest to ideality.

AB - Densities of the binary systems of 1,2-dimethylbenzene with ethyl acrylate (EA), butyl acrylate (BA), methyl methacrylate (MMA), and styrene have been measured as a function of the composition, at 298.15 K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess volumes (VE) were correlated with the Redlich-Kister equation. The excess volumes are positive for the binaries of o-xylene with MMA and styrene, and negative for o-xylene + butyl acrylate. All systems present small deviations from ideality; the system o-xylene + ethyl acrylate is closest to ideality.

KW - 1,2-Dimethylbenzene

KW - Acrylates

KW - Densities

KW - Excess volumes

KW - Monomers

KW - Styrene

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DO - 10.1016/s0040-6031(02)00605-6

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SN - 0040-6031

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JO - Thermochimica Acta

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IS - 1-2

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Volumetric properties of 1,2-dimethylbenzene + ethyl acrylate, butyl acrylate, methyl methacrylate, and styrene at 298.15 K

Abstract

Keywords

ASJC Scopus subject areas

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