Volumetric properties of 1,2-dimethylbenzene + ethyl acrylate, butyl acrylate, methyl methacrylate, and styrene at 298.15 K

René D. Peralta; Ramiro Infante; Gladis Cortez; J. Román Torres-Lubián; Jaime Wisniak

doi:10.1016/s0040-6031(02)00605-6

Volumetric properties of 1,2-dimethylbenzene + ethyl acrylate, butyl acrylate, methyl methacrylate, and styrene at 298.15 K

René D. Peralta
, Ramiro Infante
, Gladis Cortez
, J. Román Torres-Lubián
, Jaime Wisniak

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Densities of the binary systems of 1,2-dimethylbenzene with ethyl acrylate (EA), butyl acrylate (BA), methyl methacrylate (MMA), and styrene have been measured as a function of the composition, at 298.15 K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess volumes (V^E) were correlated with the Redlich-Kister equation. The excess volumes are positive for the binaries of o-xylene with MMA and styrene, and negative for o-xylene + butyl acrylate. All systems present small deviations from ideality; the system o-xylene + ethyl acrylate is closest to ideality.

Original language	English
Pages (from-to)	247-252
Number of pages	6
Journal	Thermochimica Acta
Volume	402
Issue number	1-2
DOIs	https://doi.org/10.1016/s0040-6031(02)00605-6
State	Published - 3 Jun 2003

Keywords

1,2-Dimethylbenzene
Acrylates
Densities
Excess volumes
Monomers
Styrene

ASJC Scopus subject areas

Instrumentation
Condensed Matter Physics
Physical and Theoretical Chemistry

Access to Document

10.1016/s0040-6031(02)00605-6

Cite this

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title = "Volumetric properties of 1,2-dimethylbenzene + ethyl acrylate, butyl acrylate, methyl methacrylate, and styrene at 298.15 K",

abstract = "Densities of the binary systems of 1,2-dimethylbenzene with ethyl acrylate (EA), butyl acrylate (BA), methyl methacrylate (MMA), and styrene have been measured as a function of the composition, at 298.15 K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess volumes (VE) were correlated with the Redlich-Kister equation. The excess volumes are positive for the binaries of o-xylene with MMA and styrene, and negative for o-xylene + butyl acrylate. All systems present small deviations from ideality; the system o-xylene + ethyl acrylate is closest to ideality.",

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author = "Peralta, \{Ren{\'e} D.\} and Ramiro Infante and Gladis Cortez and Torres-Lubi{\'a}n, \{J. Rom{\'a}n\} and Jaime Wisniak",

year = "2003",

month = jun,

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doi = "10.1016/s0040-6031(02)00605-6",

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pages = "247--252",

journal = "Thermochimica Acta",

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}

TY - JOUR

T1 - Volumetric properties of 1,2-dimethylbenzene + ethyl acrylate, butyl acrylate, methyl methacrylate, and styrene at 298.15 K

AU - Peralta, René D.

AU - Infante, Ramiro

AU - Cortez, Gladis

AU - Torres-Lubián, J. Román

AU - Wisniak, Jaime

PY - 2003/6/3

Y1 - 2003/6/3

N2 - Densities of the binary systems of 1,2-dimethylbenzene with ethyl acrylate (EA), butyl acrylate (BA), methyl methacrylate (MMA), and styrene have been measured as a function of the composition, at 298.15 K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess volumes (VE) were correlated with the Redlich-Kister equation. The excess volumes are positive for the binaries of o-xylene with MMA and styrene, and negative for o-xylene + butyl acrylate. All systems present small deviations from ideality; the system o-xylene + ethyl acrylate is closest to ideality.

AB - Densities of the binary systems of 1,2-dimethylbenzene with ethyl acrylate (EA), butyl acrylate (BA), methyl methacrylate (MMA), and styrene have been measured as a function of the composition, at 298.15 K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess volumes (VE) were correlated with the Redlich-Kister equation. The excess volumes are positive for the binaries of o-xylene with MMA and styrene, and negative for o-xylene + butyl acrylate. All systems present small deviations from ideality; the system o-xylene + ethyl acrylate is closest to ideality.

KW - 1,2-Dimethylbenzene

KW - Acrylates

KW - Densities

KW - Excess volumes

KW - Monomers

KW - Styrene

UR - https://www.scopus.com/pages/publications/0038206808

U2 - 10.1016/s0040-6031(02)00605-6

DO - 10.1016/s0040-6031(02)00605-6

M3 - Article

AN - SCOPUS:0038206808

SN - 0040-6031

VL - 402

SP - 247

EP - 252

JO - Thermochimica Acta

JF - Thermochimica Acta

IS - 1-2

ER -

Volumetric properties of 1,2-dimethylbenzene + ethyl acrylate, butyl acrylate, methyl methacrylate, and styrene at 298.15 K

Abstract

Keywords

ASJC Scopus subject areas

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