Volumetric properties of the ternary system dimethyl carbonate + butyl methacrylate + allyl methacrylate and its binary butyl methacrylate + allyl methacrylate at 293.15 K and p = 101.325 kPa

Jaime Wisniak, Gladis Cortez, René D. Peralta, Ramiro Infante, Luis E. Elizalde, Tláloc A. Amaro, Omar García, Homero Soto

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

Densities of the ternary system dimethyl carbonate + butyl methacrylate + allyl methacrylate and its binary subsystem butyl methacrylate + allyl methacrylate have been measured in the whole composition range, at 293.15 K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess molar volumes of the binary system are positive and were correlated with the Redlich-Kister equation and with a series of Legendre polynomials. Several models were used to correlate ternary behavior from the excess molar volume data of their constituent binaries and found to fit the data equally well. The best fit was based on a direct approach, without information on the component binary systems.

Original languageEnglish
Pages (from-to)1631-1648
Number of pages18
JournalJournal of Solution Chemistry
Volume41
Issue number9
DOIs
StatePublished - 1 Oct 2012

Keywords

  • Densities
  • Dimethyl carbonate
  • Excess molar volumes
  • Methacrylates
  • Ternary systems

ASJC Scopus subject areas

  • Biophysics
  • Biochemistry
  • Molecular Biology
  • Physical and Theoretical Chemistry

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