Volumetric properties of toluene with ethyl acrylate, butyl acrylate, methyl methacrylate, and styrene at 25°C

René D. Peralta; Ramiro Infante; Gladis Cortez; Oliverio Rodríguez; Jaime Wisniak

doi:10.1023/A:1015895807777

Volumetric properties of toluene with ethyl acrylate, butyl acrylate, methyl methacrylate, and styrene at 25°C

René D. Peralta, Ramiro Infante, Gladis Cortez, Oliverio Rodríguez, Jaime Wisniak

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

Densities of the binary systems of toluene with ethyl acrylate, butyl acrylate, methyl methacrylate, and styrene have been measured as a function of the composition, at 25°C and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densitometer. The calculated excess volumes were correlated with the Redlich-Kister equation and with a series of Legendre polynomials. The excess volumes are negative for systems toluene + (ethyl acrylate, butyl acrylate, and styrene) and positive for the system toluene + methyl methacrylate.

Original language	English
Pages (from-to)	175-186
Number of pages	12
Journal	Journal of Solution Chemistry
Volume	31
Issue number	3
DOIs	https://doi.org/10.1023/A:1015895807777
State	Published - 1 Dec 2002

Keywords

Alkyl acrylates
Densimeter
Densities
Excess volumes
Monomers
Styrene
Toluene

ASJC Scopus subject areas

Biophysics
Biochemistry
Molecular Biology
Physical and Theoretical Chemistry

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abstract = "Densities of the binary systems of toluene with ethyl acrylate, butyl acrylate, methyl methacrylate, and styrene have been measured as a function of the composition, at 25°C and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densitometer. The calculated excess volumes were correlated with the Redlich-Kister equation and with a series of Legendre polynomials. The excess volumes are negative for systems toluene + (ethyl acrylate, butyl acrylate, and styrene) and positive for the system toluene + methyl methacrylate.",

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AU - Peralta, René D.

AU - Infante, Ramiro

AU - Cortez, Gladis

AU - Rodríguez, Oliverio

AU - Wisniak, Jaime

PY - 2002/12/1

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AB - Densities of the binary systems of toluene with ethyl acrylate, butyl acrylate, methyl methacrylate, and styrene have been measured as a function of the composition, at 25°C and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densitometer. The calculated excess volumes were correlated with the Redlich-Kister equation and with a series of Legendre polynomials. The excess volumes are negative for systems toluene + (ethyl acrylate, butyl acrylate, and styrene) and positive for the system toluene + methyl methacrylate.

KW - Alkyl acrylates

KW - Densimeter

KW - Densities

KW - Excess volumes

KW - Monomers

KW - Styrene

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Volumetric properties of toluene with ethyl acrylate, butyl acrylate, methyl methacrylate, and styrene at 25°C

Abstract

Keywords

ASJC Scopus subject areas

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