Z-E isomerization of α-methylhydrazides of aromatic acids

I. D. Kalikhman; O. B. Bannikova; L. I. Volkova; R. G. Sultangareev; V. A. Lopyrev

doi:10.1007/BF00950281

Z-E isomerization of α-methylhydrazides of aromatic acids

I. D. Kalikhman, O. B. Bannikova, L. I. Volkova, R. G. Sultangareev, V. A. Lopyrev

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Abstract

The populations of the Z and E rotamers relative to the amide bond is methylhydrazides of aromatic acids are determined by concentration effects and the nature of the substituents in the aromatic ring. The values of the free ene gy of activation for Z-E isomerization varies from 13.5 to 16.0 kcal/mole and correlation with the constants of Swain and Lupton.

Original language	English
Pages (from-to)	1001-1005
Number of pages	5
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	30
Issue number	6
DOIs	https://doi.org/10.1007/BF00950281
State	Published - 1 Jan 1981
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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10.1007/BF00950281

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abstract = "The populations of the Z and E rotamers relative to the amide bond is methylhydrazides of aromatic acids are determined by concentration effects and the nature of the substituents in the aromatic ring. The values of the free ene gy of activation for Z-E isomerization varies from 13.5 to 16.0 kcal/mole and correlation with the constants of Swain and Lupton.",

author = "Kalikhman, {I. D.} and Bannikova, {O. B.} and Volkova, {L. I.} and Sultangareev, {R. G.} and Lopyrev, {V. A.}",

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AU - Kalikhman, I. D.

AU - Bannikova, O. B.

AU - Volkova, L. I.

AU - Sultangareev, R. G.

AU - Lopyrev, V. A.

PY - 1981/1/1

Y1 - 1981/1/1

N2 - The populations of the Z and E rotamers relative to the amide bond is methylhydrazides of aromatic acids are determined by concentration effects and the nature of the substituents in the aromatic ring. The values of the free ene gy of activation for Z-E isomerization varies from 13.5 to 16.0 kcal/mole and correlation with the constants of Swain and Lupton.

AB - The populations of the Z and E rotamers relative to the amide bond is methylhydrazides of aromatic acids are determined by concentration effects and the nature of the substituents in the aromatic ring. The values of the free ene gy of activation for Z-E isomerization varies from 13.5 to 16.0 kcal/mole and correlation with the constants of Swain and Lupton.

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AN - SCOPUS:34250229808

SN - 0568-5230

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JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

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ER -

Z-E isomerization of α-methylhydrazides of aromatic acids

Abstract

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