Z-E isomerization of α-methylhydrazides of aromatic acids

I. D. Kalikhman, O. B. Bannikova, L. I. Volkova, R. G. Sultangareev, V. A. Lopyrev

Research output: Contribution to journalArticlepeer-review

Abstract

The populations of the Z and E rotamers relative to the amide bond is methylhydrazides of aromatic acids are determined by concentration effects and the nature of the substituents in the aromatic ring. The values of the free ene gy of activation for Z-E isomerization varies from 13.5 to 16.0 kcal/mole and correlation with the constants of Swain and Lupton.

Original languageEnglish
Pages (from-to)1001-1005
Number of pages5
JournalBulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume30
Issue number6
DOIs
StatePublished - 1 Jun 1981
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry (all)

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