Z,E-isomerism of fluorinated mono- and diacylhydrazines

I. D. Kalikhman; P. V. Makerov; E. N. Medvedeva; T. I. Yushmanova; V. A. Lopyrev

doi:10.1007/BF00951018

Z,E-isomerism of fluorinated mono- and diacylhydrazines

I. D. Kalikhman, P. V. Makerov, E. N. Medvedeva, T. I. Yushmanova, V. A. Lopyrev

Research output: Contribution to journal › Article › peer-review

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Abstract

It was established by the¹H and¹⁹F NMR method that the insertion of fluorine atoms in the acyl radical of mono- and diacylmethylhydrazines has a substantial effect on the population of the rotamers, without noticeably changing the activation energy of the E-Z isomerization.

Original language	English
Pages (from-to)	1760-1764
Number of pages	5
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	28
Issue number	8
DOIs	https://doi.org/10.1007/BF00951018
State	Published - 1 Aug 1979
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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10.1007/BF00951018

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title = "Z,E-isomerism of fluorinated mono- and diacylhydrazines",

abstract = "It was established by the1H and19F NMR method that the insertion of fluorine atoms in the acyl radical of mono- and diacylmethylhydrazines has a substantial effect on the population of the rotamers, without noticeably changing the activation energy of the E-Z isomerization.",

author = "Kalikhman, {I. D.} and Makerov, {P. V.} and Medvedeva, {E. N.} and Yushmanova, {T. I.} and Lopyrev, {V. A.}",

year = "1979",

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T1 - Z,E-isomerism of fluorinated mono- and diacylhydrazines

AU - Kalikhman, I. D.

AU - Makerov, P. V.

AU - Medvedeva, E. N.

AU - Yushmanova, T. I.

AU - Lopyrev, V. A.

PY - 1979/8/1

Y1 - 1979/8/1

N2 - It was established by the1H and19F NMR method that the insertion of fluorine atoms in the acyl radical of mono- and diacylmethylhydrazines has a substantial effect on the population of the rotamers, without noticeably changing the activation energy of the E-Z isomerization.

AB - It was established by the1H and19F NMR method that the insertion of fluorine atoms in the acyl radical of mono- and diacylmethylhydrazines has a substantial effect on the population of the rotamers, without noticeably changing the activation energy of the E-Z isomerization.

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DO - 10.1007/BF00951018

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AN - SCOPUS:34250268083

SN - 0568-5230

VL - 28

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EP - 1764

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 8

ER -

Z,E-isomerism of fluorinated mono- and diacylhydrazines

Abstract

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