Zinc-catalyzed transamidation and esterification of N-benzoyl cytosine via C-N bond cleavage

Sujeet Gaware; Rana Chatterjee; Anant R. Kapdi; Rambabu Dandela

doi:10.1039/d3ob00697b

Zinc-catalyzed transamidation and esterification of N-benzoyl cytosine via C-N bond cleavage

Sujeet Gaware, Rana Chatterjee, Anant R. Kapdi, Rambabu Dandela

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

We have utilized N-benzoyl cytosine for efficient transamidation and esterification via catalytic C-N bond cleavage. The one-pot strategy involves the reaction of secondary amide with various aliphatic or aromatic amines and alcohols in the presence of zinc triflate and DTBP, affording diverse amides and esters in excellent yields.

Original language	English
Pages (from-to)	5176-5180
Number of pages	5
Journal	Organic and Biomolecular Chemistry
Volume	21
Issue number	25
DOIs	https://doi.org/10.1039/d3ob00697b
State	Published - 6 Jun 2023
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1039/d3ob00697b

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title = "Zinc-catalyzed transamidation and esterification of N-benzoyl cytosine via C-N bond cleavage",

abstract = "We have utilized N-benzoyl cytosine for efficient transamidation and esterification via catalytic C-N bond cleavage. The one-pot strategy involves the reaction of secondary amide with various aliphatic or aromatic amines and alcohols in the presence of zinc triflate and DTBP, affording diverse amides and esters in excellent yields.",

author = "Sujeet Gaware and Rana Chatterjee and Kapdi, \{Anant R.\} and Rambabu Dandela",

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AU - Gaware, Sujeet

AU - Chatterjee, Rana

AU - Kapdi, Anant R.

AU - Dandela, Rambabu

PY - 2023/6/6

Y1 - 2023/6/6

N2 - We have utilized N-benzoyl cytosine for efficient transamidation and esterification via catalytic C-N bond cleavage. The one-pot strategy involves the reaction of secondary amide with various aliphatic or aromatic amines and alcohols in the presence of zinc triflate and DTBP, affording diverse amides and esters in excellent yields.

AB - We have utilized N-benzoyl cytosine for efficient transamidation and esterification via catalytic C-N bond cleavage. The one-pot strategy involves the reaction of secondary amide with various aliphatic or aromatic amines and alcohols in the presence of zinc triflate and DTBP, affording diverse amides and esters in excellent yields.

UR - https://www.scopus.com/pages/publications/85163484042

U2 - 10.1039/d3ob00697b

DO - 10.1039/d3ob00697b

M3 - Article

C2 - 37293852

AN - SCOPUS:85163484042

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EP - 5180

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 25

ER -

Zinc-catalyzed transamidation and esterification of N-benzoyl cytosine via C-N bond cleavage

Abstract

ASJC Scopus subject areas

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